MersV1, Main, Exploration, bibRecord, 002493

N′-[(1E)-3-Bromo-5-chloro-2-hydroxybenzylidene]-4-tert-butylbenzohydrazide ethanol monosolvate

Identifieur interne : 002493 ( Main/Exploration ); précédent : 002492; suivant : 002494

N′-[(1E)-3-Bromo-5-chloro-2-hydroxybenzylidene]-4-tert-butylbenzohydrazide ethanol monosolvate

Auteurs : A. Thirugnanasundar [Inde] ; K. Parthipan [Inde] ; V. S. Xavier Anthonisamy [Inde] ; G. Chakkaravarthi [Inde] ; G. Rajagopal [Inde]

Source :

Acta Crystallographica Section E: Structure Reports Online [ 1600-5368 ] ; 2011.

RBID : PMC:3247593

Abstract

In the title compound, C₁₈H₁₈BrClN₂O₂·C₂H₆O, the hydroxy group forms an intramolecular O—H⋯N hydrogen bond, which influences the conformation of the Shiff base molecule, where the two aromatic rings form a dihedral angle of 21.67 (8)°. Intermolecular N—H⋯O and O—H⋯O hydrogen bonds link two Shiff base molecules and two solvent molecules into a centrosymmetric heterotetramer. Weak intermolecular C—H⋯O interactions link further tetramers related by translation along the a axis into chains.

Url:

http://www.ncbi.nlm.nih.gov/pmc/articles/PMC3247593

DOI: 10.1107/S160053681104027X
PubMed: 22219898
PubMed Central: 3247593

Affiliations:

Inde

Le document en format XML

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′-[(1<italic>E</italic>
)-3-Bromo-5-chloro-2-hydroxybenzylidene]-4-<italic>tert</italic>
-butylbenzohydrazide ethanol monosolvate</title>
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′-[(1<italic>E</italic>
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-butylbenzohydrazide ethanol monosolvate</title>
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<front><div type="abstract" xml:lang="en"><p>In the title compound, C<sub>18</sub>
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N′-[(1E)-3-Bromo-5-chloro-2-hydroxybenzylidene]-4-tert-butylbenzohydrazide ethanol monosolvate

N′-[(1E)-3-Bromo-5-chloro-2-hydroxybenzylidene]-4-tert-butylbenzohydrazide ethanol monosolvate

Source :

Abstract

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N′-[(1E)-3-Bromo-5-chloro-2-hy­droxy­benzyl­idene]-4-tert-butyl­benzo­hydrazide ethanol monosolvate

N′-[(1E)-3-Bromo-5-chloro-2-hy­droxy­benzyl­idene]-4-tert-butyl­benzo­hydrazide ethanol monosolvate

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Abstract

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N′-[(1E)-3-Bromo-5-chloro-2-hydroxybenzylidene]-4-tert-butylbenzohydrazide ethanol monosolvate

N′-[(1E)-3-Bromo-5-chloro-2-hydroxybenzylidene]-4-tert-butylbenzohydrazide ethanol monosolvate